Product ID:ALLOPRENE R10
MSDS Date:05/11/1989
FSC:6810
NIIN:00N018003
MSDS Number: BLFKL

ICI RESINS US

730 MAIN STREET
WILMINGTON, MA 01887
US

Emergency Phone: 508-658-6600

Info Phone: 508-658-6600

Preparer: ICI RESINS US (SUPP DATA)

Cage: ICIRE

ICI RESINS US

WILMINGTON, MA 01887 US

Telephone: 508-658-6600

Cage: ICIRE

CARBON TETRACHLORIDE (SARA III)

CAS: 56-23-5

RTECS: FG4900000

Fraction By Weight: 6% (CA)

OSHA PEL 10 PPM

ACGIH TLV: S,5PPM/10 STEL,A3 93

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

HR EFTS OF EXPOS. BECAUSE EXPOS POTNTL IS

RTECS: 9999999ZZ

IF HNDLD I/A/W GOOD INDUS HYGIENE PRACT, WILL NOT

RTECS: 9999999ZZ

HAVE PRDCD SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB

RTECS: 9999999ZZ

ADRENOMIMETICS MAY BE CONTRAINDICATED EXCEPT FOR

RTECS: 9999999ZZ

TO CHLOROCARBONS/CFC'S.

RTECS: 9999999ZZ

SARA TITLE III, SEC 313 AND 40 CFR 372.

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:ORAL(RAT)PROBABLY >4 G/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INGEST:SINGLE DOSE IS SLIGHTLY TOX. LG
DOSES CAN INDUCE LIVER INJURY. EYE:OCCUP EXPOS TO DUST ARE NOT
LIKELY TO IRRIT HUMANS. SKIN:NO IRRIT/SENSIT IF REL IS EXPECTED
FROM HUMAN CNTCT. CARBON TETRACHLO RIDE CAN BE ABSORB. INHAL:HIGH
DUST LEVELS CAN IRRIT UPPER RESP PASSAGES. HIGH CONC OF CARBON (SEE
EFTS OF OVEREXP)
Explanation of Carcinogenicity:CARBON TETRACHLORIDE:CLASS 2 (NTP);
CLASS 2B (IARC).
Effects of Overexposure:HLTH HAZ:TETRACHLORIDE IN AIR CAN BE ASSOC
W/CNS DEPRESS/DIZZ/VERTIGO/HDCH/MENTAL CONFUSN/INCOORD/
NAUS/VOMIT/ABDOM PAIN/DIARRHEA; INJURY TO LIVER & KIDNEY CAN ALSO
ENSUE. ACUTE/CHRONIC EXPOS CAN INDU CE LIVER & KIDNEY INJURY.
FATALITIES FROM ACUTE RENAL DMG HAVE OCCURRED IN ATM OF 1000-2000
PPM OF VAP FOR 1/2 (SUPDAT)
Medical Cond Aggravated by Exposure:PRIOR LIVER/KIDNEY DISEASE CAN BE
AGGRAVATED BY EXPOS TO CARBON TETRACHLORIDE.

First Aid:SKIN:WASH MATL OFF W/LG AMTS OF SOAP & H20. IF
REDNESS/ITCHING/BURNING SENSATION, GET MD. EYES:IMMED FLUSH W/LG
AMTS OF H20 FOR @ LST 15 MIN. IF REDNESS/ITCHING/BURNING SENSATION,
SEE MD. INGEST:DO NO T INDUCE VOMIT. GIVE ONE/TWO GLASSES OFH20 TO
DRINK & REFER TO MD. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS.
INHAL:REMOVE TO FRESH AIR. IF COUGH/OTHER RESP SYMP, CALL MD.

Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESS DEMAND SCBA &
FULL PROT EQUIP , IF INVOLVED IN FIRE OF OTHER MATERIALS.
Unusual Fire/Explosion Hazard:TOX & IRRIT THERMAL DECOMP PRODS. PROD IS
NONFLAMM, BUT THERMAL DECOMP CAN LEAVE RESIDUES WHICH ARE
SPONTANEOUSLY FLAMM IN AIR. THERMAL DECOMP PRODS MAY(SUPDAT)

Spill Release Procedures:WEAR SKIN/EYE & RESP PROT DURING CLEANUP.
SWEEP UP & RECOVER/MIX MATL W/MOIST ABSORB & SHOVEL INTO CNTNR.
WASH DOWN SPILL AREA W/HOT H20 CONTAINING DETERGENT & FLUSH TO
SEWER SERVICED BY WASTEWATER TR EATMENT FACILITY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PROVIDE GOOD VENT WHEN
HEATING/DISSOLVING IN SOLV SINCE CARBON TETRACHLORIDE MAY BE
RELEASED. DO NOT TAKE INTERNALLY. DO NOT GET IN EYES.
Other Precautions:AVOID PRLNG/RPTD CONTACT W/SKIN. DO NOT BREATHE
DUSTS. NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF ARC
WELDING/OPEN FLAMES/HOT SURF. HEAT &/UV RADIA MAY CAUSE FORM OF HCL
&/PHOSGENE . PROD SUBJECT TO REG OF TSCA, (SEE ING 7)

Respiratory Protection:USE NIOSH/MSHA APPROVED RESP FOR DUSTS, MISTS &
FUMES W/TLV NOT LESS THAN 0.05 MF/M3 IN COMBINATION W/ORGANIC VAPOR
CARTRIDGE.
Ventilation:PROVIDE LOC EXHAUST TO REMOVE CARBON TETRACHLORIDE VAP WHEN
HEATING/DISSOLVING IN SOLVENT.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NO SPECIAL REQUIREMENTS.
Work Hygienic Practices:REMOVE & WASH CONTAM CLTHG BEFORE REUSE. WASH
HANDS W/SOAP & WATER. MINIMIZE EXPOS I/A/W GOOD PRACTICE.
Supplemental Safety and Health
PREPARERS NAME:REGULATORY AFFAIRS GROUP. MP: DECOMP/CHARS W/OUT MELTING
@ 200F(93C). EXPLO HAZ:INCL HCL & PHOSGENE . MATLS TO AVOID: TEMPS
EXCEED 200C. HAZ DECOMP PROD:TETRACHLORIDE CAN FURTHER THERMALLY
DECOMP TO CHLORINE/ HCL/PHOSGENE/CO. EFT OF OVEREXP: EXPOS.
CONSUMPTION OF ALCOHOLIC BEVERAGES CAN INCR (ING 2

HCC:N1
Melt/Freeze Pt:M.P/F.P Text:(SUPP DATA)
Vapor Pres:91
Spec Gravity:1.6
Solubility in Water:INSOLUBLE
Appearance and Odor:WHITE ODORLESS POWDER
Percent Volatiles by Volume:NEGLIG

Stability Indicator/Materials to Avoid:YES
ALUMINUM CAN REACT VIOLENTLY W/PROD ABOVE 50C. DO NOT MILL DRY PROD
W/ZINC/ZINC OXIDE. VIOLENT RXN CAN OCCUR IF (SUPDAT)
Stability Condition to Avoid:DECOMPOSES ABOVE 130C.
Hazardous Decomposition Products:CARBON TETRACHLORIDE CAN BE REL BY
HEAT/ SOLV. PROD DECOMP ABOVE 130C TO CARBON TETRACHLORIDE & HCL.
CARBON (SUPP DATA)

Waste Disposal Methods:DISPOSE I/A/W LOCAL, STATE & FEDERAL
REGULATIONS. THIS PROD IS NOT HAZ WASTE UNDER RCRA REG.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.